RuCl2[(R)−DM−binap][(R)−daipen]

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产品编号:R701565

产品规格:100mg

产品价格:面议


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标准品编号: R701565
名称: RuCl2[(R)−DM−binap][(R)−daipen]
别名: [1,​1'-​(1R)​-​[1,​1'-​Binaphthalene]​-​2,​2'-​diylbis[1,​1-​bis(3,​5-​dimethylphenyl)​phosphine-​κP]​]​[(2R)​-​1,​1-​bis(4-​methoxyphenyl)​-​3-​methyl-​1,​2-​butanediamine-​κN1,​κN2]​Dichloro-ruthenium ; RuCl2[(R)-xylbinap][(R)-daipen]
CAS号: 220114-32-9
分子式: C₇₁H₇₄Cl₂N₂O₂P₂Ru
分子量: 1221.28
类别: Building Blocks; Catalyst;
应用: Chiral RuCl2(diphosphine)​(1,​2-​diamine) complexes catalyzes the asymetrical hydrogenation of amino ketones. E.g., hydrogenation of MeCOCH2NMe2 in presence of trans-​RuCl2[(R)​-​xylbinap]​[(R)​-​daipen] gave 79​% (S)​-​MeCH(OH)​CH2NMe2. This compound was used as a catalyst.
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